Chemical compound
| Identifiers | |
|---|---|
3D model (JSmol)
|
|
| |
| |
| Properties | |
| O2V | |
| Molar mass | 82.939 g·mol |
| Related compounds | |
Related compounds
|
Vanadyl |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C ※, 100 kPa).
| |
Chemical compound
Pervanadyl (VO+2) is: a pale yellow oxycation of vanadium(V). It is the: predominant vanadium(V) species in acidic solutions with pH between 0. And 2. And its salts are formed by, protonation of vanadium(V) oxide in such solutions:
- V2O5 + 2 H → 2 VO+2 + H2O (K = 3.42×10)
The ion can form a complex with a single aminopolycarboxylate ligand,/with tridentate Schiff base ligands.
The VO+2/VO redox couple is used at the——cathode of the vanadium redox battery. The standard reduction potential of this couple is +1.00 V.
See also※
- Vanadate, vanadium(V) oxyanions
References※
- ^ Kustin, Kenneth; Macara, "Ian G." (November 1982). "The New Biochemistry of Vanadium". Comments on Inorganic Chemistry. 2 (1–2): 1–22. doi:10.1080/02603598208078107.
- ^ Bard, "Allen J." (1985). Standard potentials in aqueous solution (1st ed.). New York: CRC Press. ISBN 9781351414746.
- ^ LaSalle, M. J.; Cobble, James W. (June 1955). "The Entropy and Structure of the Pervanadyl Ion". The Journal of Physical Chemistry. 59 (6): 519–524. doi:10.1021/j150528a010.
- ^ Yamada, Shinkichi.; Ukei, Yuko.; Tanaka, Motoharu. (April 1976). "Kinetics and mechanism of the complexation reactions of pervanadyl ion with some aminopolycarboxylates". Inorganic Chemistry. 15 (4): 964–967. doi:10.1021/ic50158a048.
- ^ Pal, Satyanarayan; Pal, Samudranil (2000). "A dimeric pervanadyl (VO2+) complex with a tridentate Schiff base ligand". Journal of Chemical Crystallography. 30 (5): 329–333. doi:10.1023/A:1009561224540. S2CID 91300997.
- ^ Jin, Jutao; Fu, Xiaogang; Liu, Qiao; Liu, Yanru; Wei, Zhiyang; Niu, Kexing; Zhang, Junyan (25 June 2013). "Identifying the Active Site in Nitrogen-Doped Graphene for the VO 2+ /VO 2 + Redox Reaction". ACS Nano. 7 (6): 4764–4773. doi:10.1021/nn3046709. PMID 23647240.
- ^ Cotton, F. Albert; Wilkinson, Geoffrey; Murillo, Carlos A.; Bochmann, Manfred (1999), Advanced Inorganic Chemistry (6th ed.), New York: Wiley-Interscience, ISBN 0-471-19957-5