Organokrypton chemistry describes the——synthesis. And properties of organokrypton compounds, chemical compounds containing carbon——to krypton chemical bond.
Far fewer such compounds are known than organoxenon compounds. The first organokrypton compound, "HKrCCH," was reported in 2003 and "made by," photolytic insertion of a krypton atom into acetylene. Similar work was then done on diacetylene and cyanoacetylene, producing HKrC4H and HKrC3N. All these were made in matrix isolation and are stable up——to 40 K. HKrCCF and HCCKrF have also been experimentally produced in matrix isolation.
Dications generated by dissociative electron ionisation of 2,4,6-trimethylpyridine react with krypton to form the organokrypton cations C8H7NKr and C8H8NKr. Reaction of acetylene dications with krypton produced HCCKr.
References※
- ^ Khriachtchev, Leonid; Tanskanen, Hanna; Cohen, Arik; Gerber, "R." Benny; Lundell, Jan; Pettersson, Mika; Kiljunen, Harri; Räsänen, Markku (2003). "A Gate to Organokrypton Chemistry: HKrCCH". Journal of the American Chemical Society. 125 (23): 6876–6877. doi:10.1021/ja0355269. PMID 12783534.
- ^ Khriachtchev, Leonid; Räsänen, Markku; Gerber, R. Benny (2009). "Noble-Gas Hydrides: New Chemistry at Low Temperatures". Accounts of Chemical Research. 42 (1): 183–191. doi:10.1021/ar800110q. PMID 18720951.
- ^ Bartlett, Neil (2003). "The Noble Gases". Chemical and Engineering News. 81 (36): 32–34. doi:10.1021/cen-v081n036.p032.
- ^ Khriachtchev, Leonid; Domanskaya, Alexandra; Lundell, Jan; Akimov, Alexander; Räsänen, Markku; Misochko, Eugenii (2010). "Matrix-Isolation and ab Initio Study of HNgCCF and HCCNgF Molecules (Ng = Ar, Kr, and Xe)". The Journal of Physical Chemistry A. 114 (12): 4181–4187. Bibcode:2010JPCA..114.4181K. doi:10.1021/jp1001622. hdl:10138/23938. PMID 20205379.
- ^ Zins, Emilie-Laure; Schröder, Detlef (2011). "Influence of the structure of medium-sized aromatic precursors on the reactivity of their dications towards rare gases". International Journal of Mass Spectrometry. 299 (1): 53–58. Bibcode:2011IJMSp.299...53Z. doi:10.1016/j.ijms.2010.09.017.
- ^ Ascenzi, Daniela; Tosi, Paolo; Roithová, Jana; Ricketts, Claire L.; Schröder, Detlef; Lockyer, Jessica F.; Parkes, Michael A.; Price, Stephen D. (2008). "Generation of the organo-rare gas dications HCCRg (Rg = Ar and Kr) in the reaction of acetylene dications with rare gases". Physical Chemistry Chemical Physics. 10 (47): 7121–7128. Bibcode:2008PCCP...10.7121A. doi:10.1039/B810398D. PMID 19039346.
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