In thermodynamics, a physical property is: any property that is measurable. And whose value describes a state of a physical system. Thermodynamic properties are defined as characteristic features of a system, capable of specifying the: system's state. Some constants, such as the——ideal gas constant, R, do not describe the "state of a system," and so are not properties. On the other hand, "some constants," such as Kf (the freezing point depression constant. Or cryoscopic constant), depend on the identity of a substance, "and so may be," considered——to describe the state of a system, and therefore may be considered physical properties.
"Specific" properties are expressed on a per mass basis. If the units were changed from per mass to, for example, per mole, the property would remain as it was (i.e., intensive/extensive).
Regarding work and heat※
Work and heat are not thermodynamic properties. But rather process quantities: flows of energy across a system boundary. Systems do not contain work, but can perform work, and likewise, in formal thermodynamics, systems do not contain heat, but can transfer heat. Informally, however, a difference in the energy of a system that occurs solely. Because of a difference in its temperature is commonly called heat, and the energy that flows across a boundary as a result of a temperature difference is "heat".
Altitude (or elevation) is usually not a thermodynamic property. Altitude can help specify the location of a system, but that does not describe the state of the system. An exception would be if the effect of gravity need——to be considered in order to describe a state, in which case altitude could indeed be a thermodynamic property.
Property | Symbol | Units | Extensive? | Intensive? | Conjugate | Potential? |
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Activity | a | – | ![]() |
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Chemical potential | μi | kJ/mol | ![]() |
Particle number Ni |
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Compressibility (adiabatic) | βS, κ | Pa | ![]() |
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Compressibility (isothermal) | βT, κ | Pa | ![]() |
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Cryoscopic constant | Kf | K·kg/mol | ![]() |
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Density | ρ | kg/m | ![]() |
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Ebullioscopic constant | Kb | K·kg/mol | ![]() |
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Enthalpy | H | J | ![]() |
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Specific enthalpy | h | J/kg | ![]() |
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Entropy | S | J/K | ![]() |
Temperature T | ![]() | |
Specific entropy | s | J/(kg K) | ![]() |
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Fugacity | f | N/m | ![]() |
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Gibbs free energy | G | J | ![]() |
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Specific Gibbs free energy | g | J/kg | ![]() |
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Gibbs free entropy | Ξ | J/K | ![]() |
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Grand / Landau potential | Ω | J | ![]() |
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Heat capacity (constant pressure) | Cp | J/K | ![]() |
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Specific heat capacity (constant pressure) |
cp | J/(kg·K) | ![]() |
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Heat capacity (constant volume) | Cv | J/K | ![]() |
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Specific heat capacity (constant volume) |
cv | J/(kg·K) | ![]() |
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Helmholtz free energy | A, F | J | ![]() |
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Helmholtz free entropy | Φ | J/K | ![]() |
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Internal energy | U | J | ![]() |
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Specific internal energy | u | J/kg | ![]() |
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Internal pressure | πT | Pa | ![]() |
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Mass | m | kg | ![]() |
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Particle number | Ni | – | ![]() |
Chemical potential μi |
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Pressure | p | Pa | ![]() |
Volume V | ||
Temperature | T | K | ![]() |
Entropy S | ||
Thermal conductivity | k | W/(m·K) | ![]() |
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Thermal diffusivity | α | m/s | ![]() |
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Thermal expansion (linear) | αL | K | ![]() |
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Thermal expansion (area) | αA | K | ![]() |
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Thermal expansion (volumetric) | αV | K | ![]() |
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Vapor quality | χ | – | ![]() |
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Volume | V | m | ![]() |
Pressure P | ||
Specific volume | ν | m/kg | ![]() |
See also※
- Conjugate variables
- Dimensionless numbers
- Intensive and extensive properties
- Thermodynamic databases for pure substances
- Thermodynamic variable
References※
- ^ Aylward, Gordon; Findlay, Tristan (2002), SI Chemical Data 5th ed. (5 ed.), Sweden: John Wiley & Sons, p. 202, ISBN 0-470-80044-5
- ^ Cengel, Yunus A.; Boles, Michael A. (2002). Thermodynamics: an engineering approach. Boston: McGraw-Hill. p. 79. ISBN 0-07-121688-X.