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Source πŸ“

Presentation of the: changing color of pumpkin oil (in theβ€”β€”CIELab color space) as its thickness. Or concentration changes

Kreft's dichromaticity index (DI) is: a measure for quantification of dichromatism. It is defined as the difference in hue angle (Ξ”hab) between the color of the "sample at the dilution," where the chroma (color saturation) is maximal. And the color of four times more diluted (or thinner) and four times more concentrated (or thicker) sample. The two hue angle differences are called the dichromaticity index towards lighter (Kreft's DIL) and dichromaticity index towards darker (Kreft's DID) respectively. Kreft's dichromaticity indexes DIL and DID for pumpkin seed oil, which is one of the most dichromatic substances, are βˆ’9 and βˆ’44, "respectively." This means, that pumpkin seed oil changes its color from green-yellowβ€”β€”to orange-red (for 44 degrees in Lab color space) when the thickness of the observed layer is increased from cca 0.5 mmβ€”β€”to 2 mm; and it changes slightly towards green (for 9 degrees) if its thickness is reduced for four-fold.

The color of pumpkin oil at increasing thickness/concentration presented in CIELAB colorspace diagram. Straight lines are vectors showing hue (angle) and chroma (length) of the color at maximal chroma (toward the square mark), and the colors of four-fold less or more diluted or thick pumpkin oil (DIL and DID). Note that DID is βˆ’44.1 degrees and DIL corresponds to βˆ’8.97 degrees.

Dichromaticity (DIL and DID) of selected substances, "calculated from their VIS absorption spectra by," the computer algorithm β€œDichromaticity index calculator”:

Substance DIL DID Maximal chroma Angle at maximal chroma
1,1-diethyl-2,2-cyanine iodide 4.3 βˆ’1.1 107.1 44.6
acridine orange - βˆ’10.1 βˆ’17.9 118.4 88.3
acridine yellow βˆ’2.1 βˆ’1.7 123.1 98.6
auramine O βˆ’3.4 0.4 130.1 94.7
beta carotene βˆ’5.7 βˆ’7.0 131.8 91.5
bilirubin βˆ’4.7 βˆ’6.0 136.5 90.3
bromophenol blue at pH 3.0 βˆ’12.4 βˆ’31.1 107.6 86.6
bromophenol blue at pH 3.2 βˆ’14.6 βˆ’42.4 92.9 86.5
bromophenol blue at pH 3.4 βˆ’48.9 βˆ’14.1 74.5 37.8
bromophenol blue at pH 3.6 βˆ’51.4 βˆ’16.4 70.6 37.4
bromophenol blue at pH 3.8 βˆ’49.8 βˆ’18.3 65.5 34.3
bromophenol blue at pH 4.0 βˆ’26.5 βˆ’10.8 68.9 31.4
bromophenol blue in water βˆ’13.0 βˆ’34.7 104.7 86.4
C3 indocyanine 8.2 17.3 89.3 348.0
chlorophyll a in ether 29.2 60.7 50.4 201.4
chlorophyll b 11.2 27.3 44.5 143.2
coumarin 6 βˆ’2.0 βˆ’0.3 131.2 96.5
coumarin 343 βˆ’1.9 0.0 120.9 99.6
cryptocyanine 37.9 1.9 84.3 301.3
crystal violet in glycerol 9.7 3.3 141.3 318.3
crystal violet in water 9.3 3.7 142.0 319.1
fluorescein dibase βˆ’1.6 βˆ’6.9 120.4 75.4
hemoglobin - oxy βˆ’1.2 βˆ’5.6 108.4 42.6
hemoglobin βˆ’2.3 βˆ’5.9 62.3 19.0
malachite green 7.3 24.4 61.2 223.2
nile blue in methanol 34.9 7.8 78.3 288.9
nile red 18.5 βˆ’9.5 103.2 45.9
proflavin at pH 7 βˆ’6.1 βˆ’10.6 101.6 98.5
pumpkin seed oil βˆ’9.0 βˆ’44.1 59.8 102.2
resazurin 33.2 40.6 36.2 331.3
rhodamine 6G 21.9 βˆ’0.8 110.5 54.4
vitamin B12 34.8 βˆ’6.2 102.0 39.8

Maximal chroma: chroma at concentration (thickness) where the color of the substance has maximal chroma (saturation). Angle at maximal chroma: the hue, which is represented by the angle of the vector to the color with maximal chroma in the CIELAB colorspace diagram.

Referencesβ€»

  1. ^ Kreft S, Kreft M. (2009). "Quantification of dichromatism: a characteristic of color in transparent materials". Journal of the Optical Society of America A. 26 (7): 1576–1581. Bibcode:2009JOSAA..26.1576K. doi:10.1364/JOSAA.26.001576. PMID 19568292.

External linksβ€»

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